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Headbands that convert into scarves are a great option for safaris. They'll keep sweat off your face if you're hiking or walking, but you can also use them as a scarf to keep dust out of your face. Companies like Columbia have these types of headbands. You'll be spending a lot of time in the sun, even if you're on safari in the winter. Make sure you take along a sunhat that protects your head, face, and neck from sunburn. Even with a hat, the rest of our body can be susceptible to sunburn. Sunscreen with an SPF of at least 30 should work well. You can wear your everyday shoes around your hotel, but you'll need something sturdier when you're actually out on safari. Hiking boots that come above your ankle and are waterproof are your best bet.
Select a headband that prevents sweat and dust. Pick a sunhat. Take sunscreen. Choose hiking boots.